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This coupling displaces the imine’s nitrogen in the form of ammonia, and forges a new C–N bond to produce a secondary or tertiary amine. The problem is that route generally produces a mess of ...
A single attack on an imine can lead to unsymmetrical products, while a double attack on the oxime produces symmetrical ones (J. Am. Chem. Soc. 2017, DOI: 10.1021/jacs.7b05279).
Finally. Rearrangement of the glucose-hemoglobin imine produces a more stable amine, which can be measured. I won't go into the details of how/why this works. And you won't be missing anything either.
Home Articles Alicyclic-Amine-Derived Imine-BF3 Complexes: Easy-to-Make Building Blocks for the Synthesis of Valuable α-Functionalized Azacycles ...
Researchers from the University of Tsukuba use soil bacteria as a starting point to show that copper amine oxidase can degrade cyclic imines Peer-Reviewed Publication University of Tsukuba ...
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